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O2-O2 rates

From C. Coletti and G. D. Billing, Chem. Phys. Lett. (2002)

Table III. V-V rate constants for the process O$_2$(v)+O$_2$(0) $\rightarrow$ O$_2$(v-1)+O$_2$(1) + $\Delta E$
($\Delta E$ is negative for an endothermic process)


           
$v$ $\Delta E$ (cm$^{-1}$) k $_{v,0 \rightarrow v-1,1}$

           
    100 K 300 K 500 K 700 K 1000 K

           
1 0.0 1.80E-13 8.44E-14 8.38E-14 9.83E-14 1.26E-13
2 -23.65 4.76E-14 7.10E-14 8.46E-14 8.49E-14 9.97E-14
3 -46.98 4.56E-14 8.99E-14 1.25E-13 1.62E-13 2.28E-13
5 -92.65 3.30E-14 9.03E-14 1.56E-13 2.39E-13 3.80E-13
6 -114.99 2.40E-14 9.85E-14 1.54E-13 2.09E-13 2.94E-13
8 -158.70 6.32E-15 6.08E-14 1.30E-13 2.23E-13 3.95E-13
9 -180.06 3.60E-15 5.52E-14 1.33E-13 2.23E-13 3.71E-13
12 -242.20 5.93E-16 2.81E-14 8.83E-14 1.81E-13 3.56E-13
14 -281.97 2.06E-16 1.32E-14 4.16E-14 8.87E-14 2.05E-13
15 -301.17 1.25E-16 1.27E-14 4.72E-14 1.05E-13 2.24E-13
17 -339.20 6.24E-17 7.17E-15 3.25E-14 8.90E-14 2.28E-13
20 -393.47 6.33E-18 3.17E-15 2.06E-14 6.51E-14 1.89E-13
22 -428.02 4.10E-18 1.73E-15 1.16E-14 3.99E-14 1.31E-13
23 -444.60 1.39E-18 1.60E-15 1.05E-14 3.37E-14 9.90E-14
25 -477.39 1.17E-18 8.76E-16 8.09E-15 2.88E-14 8.24E-14
26 -493.20 1.86E-19 6.65E-16 6.48E-15 2.66E-14 9.24E-14
27 -508.67 5.21E-19 5.04E-16 4.48E-15 1.81E-14 6.42E-14
28 -523.81 1.47E-18 4.73E-16 4.76E-15 1.89E-14 6.07E-14
29 -538.63 3.29E-19 3.32E-16 3.80E-15 1.71E-14 6.16E-14


Table IV. V-T rate constants for the process O$_2$(v)+O$_2$(0) $\rightarrow$ O$_2$(v-1)+O$_2$(0) +$\Delta E$
($\Delta E$ is negative for an endothermic process)


         
$v$ $\Delta E$ (cm$^{-1}$) k $_{v,0 \rightarrow v-1,0}$

         
    300 K 500 K 700 K 1000 K

         
1 1556.3 4.98E-19 8.39E-18 5.77E-17 3.00E-16
2 1532.6 9.10E-19 1.96E-17 1.53E-16 1.14E-15
3 1509.3 1.16E-18 2.83E-17 2.73E-16 1.60E-15
5 1463.7 7.33E-18 8.66E-17 4.33E-16 2.08E-15
6 1441.3 3.88E-18 6.34E-17 5.92E-16 4.14E-15
8 1397.6 1.65E-17 3.38E-16 2.56E-15 1.73E-14
9 1376.3 1.56E-17 3.43E-16 3.02E-15 1.82E-14
12 1314.1 9.74E-17 2.13E-15 1.17E-14 4.98E-14
14 1274.3 6.99E-17 1.65E-15 1.37E-14 7.35E-14
15 1254.9 1.02E-16 2.02E-15 1.39E-14 7.70E-14
17 1217.3 3.57E-16 5.90E-15 3.91E-14 1.91E-13
20 1162.8 6.34E-16 9.78E-15 6.76E-14 3.40E-13
22 1128.3 1.14E-15 1.59E-14 9.18E-14 4.58E-15
23 1111.5 1.53E-15 2.11E-14 3.37E-14 5.10E-13
25 1078.9 2.34E-15 3.48E-14 1.42E-13 5.17E-13
26 1063.1 5.79E-15 5.02E-14 2.98E-13 7.52E-13
27 1047.6 7.16E-15 7.08E-14 3.29E-13 1.13E-12
28 1032.5 7.22E-15 5.18E-14 2.42E-13 9.48E-13
29 1017.7 1.04E-14 9.78E-14 3.78E-13 1.25E-12


next up previous contents
Next: Kemi F Up: Rate constants Previous: CO-CO rates   Contents
Gert D. Billing 2002-07-01