Table III. V-V rate constants for the process O
(v)+O
(0)
O
(v-1)+O
(1) +
(
is negative for an endothermic process)
|
|
|
|
|
|
|
|
(cm) |
k
|
|
|
|
|
|
|
|
|
|
100 K |
300 K |
500 K |
700 K |
1000 K |
|
|
|
|
|
|
|
1 |
0.0 |
1.80E-13 |
8.44E-14 |
8.38E-14 |
9.83E-14 |
1.26E-13 |
2 |
-23.65 |
4.76E-14 |
7.10E-14 |
8.46E-14 |
8.49E-14 |
9.97E-14 |
3 |
-46.98 |
4.56E-14 |
8.99E-14 |
1.25E-13 |
1.62E-13 |
2.28E-13 |
5 |
-92.65 |
3.30E-14 |
9.03E-14 |
1.56E-13 |
2.39E-13 |
3.80E-13 |
6 |
-114.99 |
2.40E-14 |
9.85E-14 |
1.54E-13 |
2.09E-13 |
2.94E-13 |
8 |
-158.70 |
6.32E-15 |
6.08E-14 |
1.30E-13 |
2.23E-13 |
3.95E-13 |
9 |
-180.06 |
3.60E-15 |
5.52E-14 |
1.33E-13 |
2.23E-13 |
3.71E-13 |
12 |
-242.20 |
5.93E-16 |
2.81E-14 |
8.83E-14 |
1.81E-13 |
3.56E-13 |
14 |
-281.97 |
2.06E-16 |
1.32E-14 |
4.16E-14 |
8.87E-14 |
2.05E-13 |
15 |
-301.17 |
1.25E-16 |
1.27E-14 |
4.72E-14 |
1.05E-13 |
2.24E-13 |
17 |
-339.20 |
6.24E-17 |
7.17E-15 |
3.25E-14 |
8.90E-14 |
2.28E-13 |
20 |
-393.47 |
6.33E-18 |
3.17E-15 |
2.06E-14 |
6.51E-14 |
1.89E-13 |
22 |
-428.02 |
4.10E-18 |
1.73E-15 |
1.16E-14 |
3.99E-14 |
1.31E-13 |
23 |
-444.60 |
1.39E-18 |
1.60E-15 |
1.05E-14 |
3.37E-14 |
9.90E-14 |
25 |
-477.39 |
1.17E-18 |
8.76E-16 |
8.09E-15 |
2.88E-14 |
8.24E-14 |
26 |
-493.20 |
1.86E-19 |
6.65E-16 |
6.48E-15 |
2.66E-14 |
9.24E-14 |
27 |
-508.67 |
5.21E-19 |
5.04E-16 |
4.48E-15 |
1.81E-14 |
6.42E-14 |
28 |
-523.81 |
1.47E-18 |
4.73E-16 |
4.76E-15 |
1.89E-14 |
6.07E-14 |
29 |
-538.63 |
3.29E-19 |
3.32E-16 |
3.80E-15 |
1.71E-14 |
6.16E-14 |